Complex wave function, Chiral spin order parameter and Phase Problem

We study the two dimensional Hubbard model by use of the ground state algorithm in the Monte Carlo simulation. We employ complex wave functions as trial function in order to have a close look at properties such as chiral spin order ($\chi$SO) and flux phase. For half filling, a particle-hole transformation leads to sum rules with respect to the Green's functions for a certain choice of a set of wave functions. It is then analytically shown that the sum rules lead to the absence of the $\chi$SO. Upon doping, we are confronted with the sign problem, which in our case %ch appears as a ``phase problem" due to the phase of the Monte Carlo weights. The average of the phase shows an exponential decay as a function of inverse temperature similarly to that of sign by Loh Jr. et. al. . We compare the numerical results with those of exact numerical calculations.Comment: 28 pages, 9 figures(hard copy will be available upon request

Phase separation in the vicinity of the surface of κ\kappa-(BEDT-TTF)2_2Cu[N(CN)2_2]Br by fast cooling

Partial suppression of superconductivity by fast cooling has been observed in the organic superconductor $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Br by two means: a marked sample size effect on the magnetic susceptibility and direct imaging of insulating regions by scanning microregion infrared reflectance spectroscopy. Macroscopic insulating regions are found in the vicinity of the crystalline surface after fast cooling, with diameters of 50--100 $\mu$m and depths of a few $\mu$m. The very large in-plane penetration depth reported to date ($\sim$ 24--100 $\mu$m) can be explained by the existence of the insulating regions.Comment: Several rhetoric alternations to avoid misleadings. 6 pages, 3 figures. to be publihsed in Phys. Rev.

Imaging phase separation near the Mott boundary in the correlated organic superconductors κ\kappa-(BEDT-TTF)2_{2}X

Electronic phase separation consisting of the metallic and insulating domains with 50 -- 100 $\mu$m in diameter is found in the organic Mott system $\kappa$-[($h$8-BEDT-TTF)$_{1-x}$($d$8-BEDT-TTF)$_{x}$]$_{2}$Cu[N(CN)$_{2}$]Br by means of scanning micro-region infrared spectroscopy using the synchrotron radiation. The phase separation appears below the critical end temperature 35 -- 40 K of the first order Mott transition. The observation of the macroscopic size of the domains indicates a different class of the intrinsic electronic inhomogeneity from the nano-scale one reported in the inorganic Mott systems such as High-$T_{c}$ copper and manganese oxides.Comment: 4 pages, 3 figure

Relaxor ferroelectricity induced by electron correlations in a molecular dimer Mott insulator

We have investigated the dielectric response in an antiferromagnetic dimer-Mott insulator beta'-(BEDT-TTF)2ICl2 with square lattice, compared to a spin liquid candidate kappa-(BEDT-TTF)2Cu2(CN)3. Temperature dependence of the dielectric constant shows a peak structure obeying Curie-Weiss law with strong frequency dependence. We found an anisotropic ferroelectricity by pyrocurrent measurements, which suggests the charge disproportionation in a dimer. The ferroelectric actual charge freezing temperature is related to the antiferromagnetic interaction, which is expected to the charge-spin coupled degrees of freedom in the system.Comment: 5 pages, 4 figures, to be published in Phys. Rev.

Optical probe of carrier doping by X-ray irradiation in organic dimer Mott insulator κ\kappa-(BEDT-TTF)2_{2}Cu[N(CN)2]_{2}]Cl

We investigated the infrared optical spectra of an organic dimer Mott insulator $\kappa$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]Cl, which was irradiated with X-rays. We observed that the irradiation caused a large spectral weight transfer from the mid-infrared region, where interband transitions in the dimer and Mott-Hubbard bands take place, to a Drude part in a low-energy region; this caused the Mott gap to collapse. The increase of the Drude part indicates a carrier doping into the Mott insulator due to irradiation defects. The strong redistribution of the spectral weight demonstrates that the organic Mott insulator is very close to the phase border of the bandwidth-controlled Mott transition.Comment: 4 pages, 4 figure